Probing Oxide-Ion Mobility in the Mixed Ionic–Electronic Conductor La2NiO4+δ by Solid-State 17O MAS NMR Spectroscopy

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Probing Oxide-Ion Mobility in the Mixed Ionic–Electronic Conductor La2NiO4+δ by Solid-State 17O MAS NMR Spectroscopy

While solid-state NMR spectroscopic techniques have helped clarify the local structure and dynamics of ionic conductors, similar studies of mixed ionic-electronic conductors (MIECs) have been hampered by the paramagnetic behavior of these systems. Here we report high-resolution (17)O (I = 5/2) solid-state NMR spectra of the mixed-conducting solid oxide fuel cell (SOFC) cathode material La2NiO4+...

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ژورنال

عنوان ژورنال: Journal of the American Chemical Society

سال: 2016

ISSN: 0002-7863,1520-5126

DOI: 10.1021/jacs.6b07348